43,600 research outputs found
Universal Ratios of Characteristic Lengths in Semidilute Polymer Solutions
We use experimental and simulation data from the literature to infer five
characteristic lengths, denoted , , , , and
of a semidilute polymer solution. The first two of these are defined in
terms of scattering from the solution, the third is defined in terms of osmotic
pressure, the fourth by the spatial monomer concentration profile, and the last
by co-operative diffusion. In a given solution the ratios of any of these five
lengths are expected to be universal constants. Knowing these constants thus
allows one to use one measured property of a solution as a means of inferring
others. We calculate these ratios and estimate their uncertainties for
solutions in theta as well as good-solvent conditions. The analysis is
strengthened by use of scattering properties of isolated polymers inferred from
computer simulations.Comment: 15 pages(pdf), to be submitted to Macromolecules or J. Chem. Phy
Three undescribed pathogenic Phytophthora taxa from the south-west of Western Australia
The Phytophthora culture collection of the Vegetation Health Service of the Department of Environment and Conservation of Western Australia (WA) has been re-evaluated using DNA sequencing (Burgess et al., 2009). This has revealed many undescribed taxa previously classified as known morpho-species, one of which has recently been described as P. multivora (Scott et al., 2009).
The aim of this study was to describe three of these taxa, all of which occur in WA native ecosystems. They were compared with both the morphological species to which they are most similar and their closest phylogenetic relatives. In addition, the pathogenicity of these taxa was assessed in glasshouse trials
Theory of inter-edge superexchange in zigzag edge magnetism
A graphene nanoribbon with zigzag edges has a gapped magnetic ground state
with an antiferromagnetic inter-edge superexchange interaction. We present a
theory based on asymptotic properties of the Dirac-model ribbon wavefunction
which predicts and ribbon-width dependencies for the
superexchange interaction strength and the charge gap respectively. We find
that, unlike the case of conventional atomic scale superexchange, opposite
spin-orientations on opposite edges of the ribbon are favored by both kinetic
and interaction energies.Comment: 4 pages 8 figure
Magneto-electric coupling in zigzag graphene nanoribbons
Zigzag graphene nanoribbons can have magnetic ground states with
ferromagnetic, antiferromagnetic, or canted configurations, depending on
carrier density. We show that an electric field directed across the ribbon
alters the magnetic state, favoring antiferromagnetic configurations. This
property can be used to prepare ribbons with a prescribed spin-orientation on a
given edge.Comment: 4 pages, 5 figure
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The Effect of Inkjet Ink Composition on Rheology And Jetting Behaviour
This work presents recent results on the way linear and non linear viscoelastic properties of the fluids affect the jetting
mechanism. Recent progress on quantitative characterising both high frequency linear (LVE) and non-linear (NLVE) viscoelasticity
of fluids allows fluids to be assessed for their jettability before using such materials in a DoD print head. In term of linear viscoelastic measurements, the Piezo Axial Vibrator (PAV) was used to probe the rheology of the fluids on a frequency range
between 10Hz and 10000Hz. A filament stretching apparatus, called the âCambridge Trimasterâ, was used in combination with
high speed cinematography, to characterize the fluids high speed stretching and break-up behaviour. The series of fluids investigated here consist in dilutions of mono disperse polystyrene with different molecular weight (110, 210, 306 and 488 kg/mol respectively) diluted in diethyl phthalate. The choice of polymer weights and concentrations were chosen to match both the
complex viscosity and the LVE. However, non linear rheological data experiments exhibit differences in the fluid relaxation time
and filament break-up mechanism. Ultra-high speed cinematography of DoD jetting events were correlated with filament break-up experiments and demonstrated that fluid rheology provides valuable information on the jetting quality of the fluids
Quantum and classical echoes in scattering systems described by simple Smale horseshoes
We explore the quantum scattering of systems classically described by binary
and other low order Smale horseshoes, in a stage of development where the
stable island associated with the inner periodic orbit is large, but chaos
around this island is well developed. For short incoming pulses we find
periodic echoes modulating an exponential decay over many periods. The period
is directly related to the development stage of the horseshoe. We exemplify our
studies with a one-dimensional system periodically kicked in time and we
mention possible experiments.Comment: 7 pages with 6 reduced quality figures! Please contact the authors
([email protected]) for an original good quality pre-prin
Shot noise of a quantum dot measured with GHz stub impedance matching
The demand for a fast high-frequency read-out of high impedance devices, such
as quantum dots, necessitates impedance matching. Here we use a resonant
impedance matching circuit (a stub tuner) realized by on-chip superconducting
transmission lines to measure the electronic shot noise of a carbon nanotube
quantum dot at a frequency close to 3 GHz in an efficient way. As compared to
wide-band detection without impedance matching, the signal to noise ratio can
be enhanced by as much as a factor of 800 for a device with an impedance of 100
k. The advantage of the stub resonator concept is the ease with which
the response of the circuit can be predicted, designed and fabricated. We
further demonstrate that all relevant matching circuit parameters can reliably
be deduced from power reflectance measurements and then used to predict the
power transmission function from the device through the circuit. The shot noise
of the carbon nanotube quantum dot in the Coulomb blockade regime shows an
oscillating suppression below the Schottky value of , as well an
enhancement in specific regions.Comment: 6 pages, 4 figures, supplementar
Large thermomagnetic effects in weakly disordered Heisenberg chains
The interplay of different scattering mechanisms can lead to novel effects in
transport. We show theoretically that the interplay of weak impurity and
Umklapp scattering in spin-1/2 chains leads to a pronounced dip in the magnetic
field dependence of the thermal conductivity at a magnetic field . In sufficiently clean samples, the reduction of the magnetic
contribution to heat transport can easily become larger than 50% and the effect
is predicted to exist even in samples with a large exchange coupling, J >> B,
where the field-induced magnetization is small. Qualitatively, our theory might
explain dips at observed in recent heat transport measurements on
copper pyrazine dinitrate, but a fully quantitative description is not possible
within our model.Comment: 5 pages, 2 figure
Collective effects in charge transfer within a hybrid organic-inorganic system
A collective electron transfer (ET) process was discovered by studying the
current noise in a field effect transistor with light-sensitive gate formed by
nanocrystals linked by organic molecules to its surface. Fluctuations in the ET
through the organic linker are reflected in the fluctuations of the transistor
conductivity. The current noise has an avalanche character. Critical exponents
obtained from the noise power spectra, avalanche distributions, and the
dependence of the average avalanche size on avalanche duration are consistent
with each other. A plausible model is proposed for this phenomenonComment: 15 pages 4 figures. Accepted for publication in Physical Review
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